Controllable electrodeposition synthesis of Pd/TMxOy-rGO/CFP composite electrode for highly efficient methanol electro-oxidation

A novel and high-efficiency Pd/TM_xO_y-rGO/CFP (TM_xO_y = Co₃O₄, Mn₃O₄, Ni(OH)₂) electrocatalyst for directly integrated membrane electrode was synthesized by controllable cyclic voltammetry electrodeposition combined with hydrothermal process. The results showed excellent performance towards methanol oxidation reduction. The Pd/Co₃O₄-rGO/CFP as-prepared catalyst has the best electrocatalytic activity, and mass activity is 5181 mA·mg⁻¹_Pd, which is about 40 times and 4.3 times that of the commercial Pd/C and Pt/C catalyst (JM). It can be attributed that the small size of Pd nanoparticle, uniformity of distribution, and the synergistic interaction between transition metal oxide on the support surface and Pd nanoparticles. The prepared Pd/TM_xO_y-rGO/CFP composite electrode is a promising catalyst for integrated membrane electrode assembly of proton exchange membrane fuel cells in the future.     

EFPI-FBG复合光纤传感器高温大应变试验研究

由于缺乏航空发动机/燃气轮机服役环境下叶片温度、应变有效性检测的技术与装置，所以工作叶片的温度环境、载荷环境和应变分布等关键数据的缺失是故障检修工作中的最大困难之一。采用非本征型法布里-珀罗(Extrinsic Farby Perot Interferometric,EFPI)与光纤光栅(Fiber Bragg Grating,FBG)传感技术，研制了一种基于单模光纤的EFPI FBG复合光纤传感器及其解调设备。通过搭建高温拉伸试验平台，开展了基于DZ125材料试件的复合光纤传感器高温、大应变测量的性能测试。试验结果表明：复合光纤传感器的工作温度范围为26 ℃~1 100 ℃，温度测量精度不超过全量程的5%，分辨率为0.066 ℃；F-P传感器的应变测量范围为0~19 468 με，在1 100 ℃下的相对误差为1.96%，分辨率为0.053 με。     

From sustainability to sustainizability

Following the recent introduction of the Sustainability over Sets (SOS) concept as a sustainability analysis tool with broad flexibility in incorporating human input, in this work, the concepts of Sustainizability (SIZ) and Sustainizability over Sets (SIZOS) are introduced, as novel frameworks for sustainable system synthesis. Springing off the conceptual foundation of sustainability, SIZ (and SIZOS) refers to the existence of allowable external actions, and/or design changes that can render sustainable (sustainable over a set) an unsustainable (unsustainable over a set) system. Utilizing earlier mathematical results for SOS, rigorous necessary and sufficient conditions for SIZOS are presented. Two case studies, on a two-dimensional biological waste treatment system, and a three-dimensional food chain system, are then presented to illustrate the developed necessary and sufficient conditions for SIZOS.     

碳纤维复合材料薄壁圆筒的轴向导热系数测试

碳纤维复合材料薄壁圆筒为各向异性导热，其轴向导热系数是筒体温度场理论计算、成型工艺优化的重要参数。碳纤维复合材料圆筒由于较小的截面面积给筒体加热、热量有效传递带来了较大困难。本文以平板材料导热系数的稳态法测试国家标准为基础，基于傅里叶一维稳态导热原理，设计了一套用于薄壁圆筒轴向导热系数测试的装置，采用双试件对称加热、辐射换热防护及热对流环境控制等实现了热量沿筒体轴向的有效传导，利用该装置对导热系数已知的铝筒进行测试，验证了该装置设计的可行性，得到了碳纤维复合材料薄壁圆筒的轴向导热系数为（4.60±0.13） W/(m•K)。     

基于间隔理论的过采样集成算法

针对传统集成算法不适用于不平衡数据分类的问题，提出基于间隔理论的AdaBoost算法（MOSBoost）。首先通过预训练得到原始样本的间隔；然后依据间隔排序对少类样本进行启发式复制，从而形成新的平衡样本集；最后将平衡样本集输入AdaBoost算法进行训练以得到最终集成分类器。在UCI数据集上进行测试实验，利用F-measure和G-mean两个准则对MOSBoost、AdaBoost、随机过采样AdaBoost（ROSBoost）和随机降采样AdaBoost（RDSBoost）四种算法进行评价。实验结果表明，MOSBoost算法分类性能优于其他三种算法，其中，相对于AdaBoost算法，MOSBoost算法在F-measure和G-mean准则下分别提升了8.4%和6.2%。     

Mechanical properties of continuous bamboo fiber-reinforced biobased polyamide 11 composites

This study is devoted to the analysis of the properties of continuous bamboo fiber (BF)-reinforced polyamide 11 (PA 11) composites. The SEM observations highlighted continuity between BFs and the polymeric matrix showing a high density of hydrogen bonds. The comparative calorimetric study of the matrix and its composites showed that the crystallinity of PA 11 was not modified by the presence of bamboo fibers. The physical aging observed in PA 11 is no more observed in composites due to physical interactions between PA 11 and BFs. The mechanical properties were investigated by tensile strength and dynamic mechanical analysis. The introduction of BFs enhanced Young's modulus of the matrix by a factor of 10. The presence of BFs also improved the storage shear modulus G′ over the whole temperature range. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47623.     

高功率光纤激光器光纤器件封装应力影响研究

高功率激光器无源器件制作过程中封装不当引入的应力,会导致信号光光束质量劣化和光纤温升,为了解决此问题,理论分析了光纤形变对信号光模式分布的影响,利用有限元方法建立包层光导致光纤发热模型,实验研究了不同封装方式对光纤发热情况和信号光光束质量的影响。实验表明,应力导致的光纤形变会造成信号光M2值在受力方向上略微变小而其垂直方向上变大,在输出100 W信号光时,施加应力导致的M2值的变化最高为0.39,与仿真结果相符。在光纤温升方面,相比于使用硬质胶水带来的12 ℃温升,使用硅橡胶封装的剥离器将温升控制在5 ℃以内,且其封装应力引入的M2值的变化在0.05以内。     

DP980高强钢连续退火后的组织与性能

研究了不同工艺参数对980 MPa级连续退火双相钢组织及力学性能的影响,利用光学显微镜、透射电镜(TEM)以及拉伸试验对双相钢的微观组织和力学性能进行测试及分析。结果表明:DP980钢的退火组织主要由铁素体、马氏体岛和少量的贝氏体组成,马氏体岛附近的位错密度较高。随着均热温度的升高,DP980钢的抗拉强度呈现先降低后升高的趋势,屈服强度与抗拉强度的趋势一致,伸长率先升高后降低。随着过时效温度的升高,DP980钢的抗拉强度和屈服强度降低,降低幅度较小,伸长率上升,但变化不明显,说明通过调整过时效温度来调控其力学性能的作用较小。